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Five Flags Pyrotechnics Permit
Copyrighted June 20, 2023 City of Dubuque Consent Items # 017. City Council Meeting ITEM TITLE: Five Flags Pyrotechnics Permit SUMMARY: City Manager recommending City Council approval of a Pyrotechnic Permit as submitted by the Five Flags Center for a pyrotechnics display at music performance on July 1, 2023. SUGGESTED Suggested Disposition: Receive and File; Approve DISPOSITION: ATTACHMENTS: Description MVM Memo Five Flags Pyrotechnics Permit Memo Request for Permit Flame Effect Plan Type City Manager Memo Staff Memo Supporting Documentation Supporting Documentation THE C DUjIBQTE Masterpiece on the Mississippi TO: The Honorable Mayor and City Council Members FROM: Michael C. Van Milligen, City Manager SUBJECT: Five Flags Pyrotechnics Permit DATE: June 15, 2023 Dubuque WAWca 914 ii 2007-2012.2013 2017*2019 Fire Marshal Kevin Esser is recommending City Council approval of a Pyrotechnic Permit as submitted by the Five Flags Center for a pyrotechnics display at music performance on July 1, 2023. I concur with the recommendation and respectfully request Mayor and City Council approval. v Mic ael C. Van Milligen MCVM:sv Attachment cc: Crenna Brumwell, City Attorney Cori Burbach, Assistant City Manager Amy Scheller, Fire Chief Kevin Esser, Fire Marshal THE CITY OF DUB E-E Masterpiece on the Mississippi TO: Mike Van Milligen, City Manager FROM: Kevin Esser, Fire Marshal DATE: June 15, 2023 RE: Five Flags Pyrotechnics Permit INTRODUCTION Dubuque AII•Ameft City �I 2007-2012.2013 2017*2019 The Five Flags has applied for a permit to use pyrotechnics at a music performance on July 1, 2023. Pyrotechnic permits require the approval of the City Council prior to permit issuance. BACKGROUND A permit application has been received for a pyrotechnics display at the Koe Wetzek performance taking place at the Five Flags Center on July 1, 2023. The pyrotechnics will be operated by an experienced and licensed pyrotechnics operator. All required documents have been submitted including a certificate of liability, a site plan, types and quantities of pyrotechnics, a safety plan, and the operator's qualifications and experience. The Five Flags center has agreed to pay overtime for 2 firefighters to standby during the performance. RECOMMENDATION I recommend the City Council's approval of the Pyrotechnic Permit submitted by the Five Flags Center for July 1, 2023. cc: Amy Scheller, Fire Chief Star S Productions SFX 1224 Corporate Dr. W. Ste F. P�w pmmt i AWfimfiem Arlington, TX 76005 Request for Permit To: Fire Marshal's Office From: Jamie Smith: Star S Productions SFX Offices: 817-652-3555 Mobile: 214-549-1064 starsp@wt.net A. Person, group, organization sponsoring event: Koe Wetzel Productions Location of Production: Five Flags Center 405 Main St, Dubuque, IA 52001 B. Date and time of Production: July 1, 2023 Koe Wetzel Band Est Time: 9:30-11:00 C. Date and time of rehearsal & demo for AHJ: July 1, 2023, at 4pm D. Pyrotechnic Operator: Wes Richardson —Star S Productions SFX Contact number: 325-276-1329 Over 8 yrs. of experience E. Licenses held by Operator: Texas SEO 2959652 Texas FEO 2959651 Attached: Product Description Sight Plans Copy of Insurance Copy of licenses SIDS Product Description: Item Name Altitude Duration Performance Quantity Stage Flames 8' -15' 1-second burst Column of Fire 6 G Flames 8'- 15' 1 second burst Column of Fire 6 Mines 25' 1 second burst Projection of colored stars 48 Air Burst 25-30' Trim 1 second each 8-10' Burst and flash of aluminum sparks 24 201b Propane Tanks 4 • Airburst are manufactured by RES • Mines are manufactured by Ultratec • SDS Sheets attached • Product has no fallout with no clean up necessary • Product should be stored on site in a locked pyro room provided by venue • Control is Pyromate Digital Controller, PPII Airburst Controller and DMX Control Board Overview: • We will provide pyro augmentations for the Koe Wetzel Band • We will provide 6 Stage Flames that operate on 4- 201b propane tanks • We will provide 6 G Flames that operate on 2- 600ml fuel canisters • We will provide 48- 25ft Mines • We will provide 24 Low Altitude Airburst • Fire Extinguishers: 2 H2O, 2 BC • Placement of extinguishers determined once we are on site See attached SFX Stage Site Plans r, b ��, Xis i �• �r �� .-pm % T f �+ P# A• * �S 4.1 1 10' Koe Wetzel SFX Site Plan Overhead View Stage Flame G-Flame 1 25' Mines Mines & tage Flames 30ft + to Odge of stage 8-10' Low Altitude Airburst Mines & Stage Flames are 30ft plus to edge of stage. Airburst Truss is 26ft Trim and 15ft from downstage edge Barricade is an additional 12ft from edge of stage. I4 I6 Ilp 0 � + 12ft to barricade Airburst Truss 15ft to edge of stage 0 0 kv q Truss Trim 26ft plus ACORN® CERTIFICATE OF LIABILITY INSURANCE DATE (MMIDD/YYYY) � 6/15/2023 THIS CERTIFICATE IS ISSUED AS A MATTER OF INFORMATION ONLY AND CONFERS NO RIGHTS UPON THE CERTIFICATE HOLDER. THIS CERTIFICATE DOES NOT AFFIRMATIVELY OR NEGATIVELY AMEND, EXTEND OR ALTER THE COVERAGE AFFORDED BY THE POLICIES BELOW. THIS CERTIFICATE OF INSURANCE DOES NOT CONSTITUTE A CONTRACT BETWEEN THE ISSUING INSURER(S), AUTHORIZED REPRESENTATIVE OR PRODUCER, AND THE CERTIFICATE HOLDER. IMPORTANT: If the certificate holder is an ADDITIONAL INSURED, the policy(ies) must be endorsed. If SUBROGATION IS WAIVED, subject to the terms and conditions of the policy, certain policies may require an endorsement. A statement on this certificate does not confer rights to the certificate holder in lieu of such endorsement(s). PRODUCER CONTACT NAME: Acrisure, LLC dba Britton Gallagher & Associates PHONE FAX One Cleveland Center, Floor 30 A/C No Ext : 216-658-7100 A/C No): 216-658-7101 ADDRESS: 1375 East 9th Street INSURER(S) AFFORDING COVERAGE NAIC # Cleveland OH 44114 INSURERA: Texas Mutual Insurance Company INSURED INSURER B: Everest Indemnity Insurance Co. 10851 Star S Productions Inc. 1224 Corporate Dr West, Suite F INSURER C : Everest Denali Insurance Company 16044 INSURERD: Arch Speciality Ins Co 21199 Arlington TX 75006 INSURER E : INSURER F : COVERAGES CERTIFICATE NUMBER: 1341738204 REVISION NUMBER: THIS IS TO CERTIFY THAT THE POLICIES OF INSURANCE LISTED BELOW HAVE BEEN ISSUED TO THE INSURED NAMED ABOVE FOR THE POLICY PERIOD INDICATED. NOTWITHSTANDING ANY REQUIREMENT, TERM OR CONDITION OF ANY CONTRACT OR OTHER DOCUMENT WITH RESPECT TO WHICH THIS CERTIFICATE MAY BE ISSUED OR MAY PERTAIN, THE INSURANCE AFFORDED BY THE POLICIES DESCRIBED HEREIN IS SUBJECT TO ALL THE TERMS, EXCLUSIONS AND CONDITIONS OF SUCH POLICIES. LIMITS SHOWN MAY HAVE BEEN REDUCED BY PAID CLAIMS. INSR LTR TYPE OF INSURANCE ADDL INSR SUBR WVD POLICY NUMBER POLICY EFF MM/DD/YYYY POLICY EXP MM/DD/YYYY LIMITS B GENERAL LIABILITY Y Y S18GL00260-221 12/29/2022 12/29/2023 EACH OCCURRENCE $ 1,000,000 X COMMERCIAL GENERAL LIABILITY DAMAGE(RENTED PREMISESS Ea occurrence) $ 500,000 CLAIMS -MADE OCCUR MED EXP (Any one person) $ PERSONAL & ADV INJURY $ 1,000,000 GENERAL AGGREGATE $ 2,000,000 GEN'L AGGREGATE LIMIT APPLIES PER: PRODUCTS - COMP/OP AGG $ 2,000,000 POLICY X PRO- JECT LOC $ C AUTOMOBILE LIABILITY Y Y S18CA00100-221 12/29/2022 12/29/2023 COMBINED SINGLE LIMIT Ea accident $ 1 000 000 X BODILY INJURY (Per person) $ ANY AUTO ALL OWNED SCHEDULED AUTOS AUTOS BODILY INJURY (Per accident) $ X PROPERTY DAMAGE Per accident $ HIRED AUTOS X NON -OWNED AUTOS D UMBRELLA LIAB X OCCUR Y Y UXP1041842-02 12/29/2022 12/29/2023 EACH OCCURRENCE $ 4,000,000 X AGGREGATE $ 4,000,000 EXCESS LAB CLAIMS -MADE DED RETENTION $ $ A WORKERS COMPENSATION AND EMPLOYERS' LIABILITY Y / N Y 0001229969 10/15/2022 10/15/2023 X WC STATUS OTH- TORY LIMITS ER ANY PROPRIETOR/PARTNER/EXECUTIVE E.L. EACH ACCIDENT $ 500,000 OFFICER/MEMBER EXCLUDED? ❑ N / A (Mandatory in NH) E.L. DISEASE - EA EMPLOYEE $ 500,000 If yes, describe under DESCRIPTION OF OPERATIONS below E.L. DISEASE - POLICY LIMIT $ 500,000 B Excess Liability #2 Y Y S18EX01555-221 12/29/2022 12/29/2023 Each Occ/ Aggregate $5,000,000 Total Limits $10,000,000 DESCRIPTION OF OPERATIONS I LOCATIONS / VEHICLES (Attach ACORD 101, Additional Remarks Schedule, if more space is required) Additional Insured extension of coverage is provided by above referenced General Liability policy where required by written agreement. For the use of pyrotechnics for the Koe Wetzel Band on July 1, 2023. The certificate holder, the City Of Dubuque, including all its' elected and appointed officials, its' employees and volunteers, all its' boards, commissions and/or authorities and board members, employees, and volunteers are included an additional insured where required by contract. CERTIFICATE HOLDER CANCELLATION SHOULD ANY OF THE ABOVE DESCRIBED POLICIES BE CANCELLED BEFORE THE EXPIRATION DATE THEREOF, NOTICE WILL BE DELIVERED IN ACCORDANCE WITH THE POLICY PROVISIONS. Five Flags Center 405 Main Street AUTHORIZED REPRESENTATIVE DUBUQUE IA 52001 ©1988-2010 ACORD CORPORATION. All rights reserved. ACORD 25 (2010/05) The ACORD name and logo are registered marks of ACORD Federal Explosives License/Permit U.S. Department of Justice Bureau of Alcohol, Tobacco, Firearms and Explosives (18 U.S. C Chapter 40) In accordance with the provisions of Title XI, Organized Crime Control Act of 1970, and the regulations issued thereunder (27 CFR Part 555), you may engage in the activity specified in this license or permit within the limitations of Chaptea400 United States Code and the regulations issued thereunder, until the expiration date shown. THIS LICENSE IS NOT TRANSFERAB16 11ERA See "WARNINGS" and "NOTICES" on reverse. Direct ATF ATF - Chief, FELC Correspondence To 244 Needy Road 5-BL--1 • • • Martinsburg, WV 25405-31 Chief,Federal Explosives Licensing Centej(FELCj K Expira Name STAR S PRODUCTIONS Premises Address (Changes? Notify 1224 CORPORATE DRI1 ARLINGTON TX 76006- Type of License or Permit 19-MANUFACTU14ER OF EXP2,10C Purchasing Certificatio The licensee or permittee named above shall use,, ` transferor of explosives to verify the identity and the permittee as provided by 27 CFR Part 555. The sigma signature. A faxed, scanned or e-mailed copy of the lii intended to be an original signature is acceptable. The Explosives Licensee (FEL) or a responsible person of 1 copy of a license or permit issued to the licensee or per businessVr operations specified abojgA"Type of Responsible Person Signature Date ofthe Fed"' "4 STAR i a true 1 7 ., S FELC of any changes.) pro WEST SUITE F P0 LnAlr� �A.TEFcwn �aiut0o15Pact L__� Previous Edition is Obsolete STM s Feoouonoes INC12ea CORPO TE URP E WMT surrE F:76=:&BL-194F•1xesr:.mm r, =4.19-MUFAMREB OF EXPLOSIVES Revised September 2011 Federal Explosives license (FEL) Customer Service Information Federal Explosives Licensing Center (FELC) Toll -free Telephone Number: (877) 283-3352 ATF Homepage: www.atfgov 244 Needy Road Fax Number: (304) 616-4401 Martinsburg, WV 25405-9431 E-mail: FELC@atfgov Change of Address (27 CFR 555.54(a) (1)) . Licensees or permittees may during the term of their current license or permit remove their business or operations to a new location at which they intend regularly to carry on such business or operations. The licensee or permittee is required to give notification of the new location of the business or operations not less than 10 days prior to such removal with the Chief, Federal Explosives Licensing Center. The license or permit will be valid" for the remainder of the term of the original license or permit. (The Chief, FELC, shall, if the licensee or permittee is not qualified, refer the request for amended license or permit to the Director of Industry Operations for denial in accordance with § 555.54.) Right of Succession (27 CFR 555.59). (a) Certain persons other than the licensee or permittee may secure the right to carry on the same explosive materials business or operations at the same address shown on, and for the remainder of the term of, a current license or permit. Such persons are: (1) The surviving spouse or child, or executor, administrator, or other legal representative of a deceased licensee or perwittee; and (2) A receiver or trustee in bankruptcy, or an assignee for benefit of creditors. (b) In order to secure the right provided by this section, the person or persons continuing the business or operations shall furnish the license or permit for for that business or operations for endorsement of such succession to the Chief, FELC, within 30 days from the date on which the successor begins to carry on the business or operations. (Continued on reverse side) Cut Here X ,- ------------------------------, Wesley Richardson McKinney/San Angelo, Texas 325-276-1329 US Navy Veteran DRIVER LICENSE 15628498 C .07131/2019 E,p 1011' Dos 10J1711983 + PICHAROSON WESLEY ALLEN 3037 STALLION DR ROBINSON TX 76706-0000 +2 Resmchons NONE »End NONE +c H9t 6*-04" i. fie. M In Ere. BLU 5 DD 09610920079321046538 Pyrotechnics Experience • Koe Wetzel National Tour 2022 • Bout in the Ballpark, Globe Life Field 2022-2023 • Dallas Cowboys Christmas Spectacular 2022 • Whites Chapel Christmas Fireworks Spectacular 2022 • AT&T 5G Roadshow, AT&T Stadium 2021-2022 • Six Flags Over Texas New Year's Show, Dallas Texas 2022 • Duncanville, Texas 4th of July Show 2022 • San Angelo Pops Concert and 4th of July Show 2022 • San Angelo Stock Show and Rodeo 2015 — present • Angelo State University Baseball 2015 — present • Angelo State University Softball 2015 — present • Angelo State University Football 2015 - present FIREWORKS SPECIAL EFFECTS OPERATOR'S LICENSE TEXAS DEPARTMENT OF INSURANCE STATE FIRE MARSHAL'S OFFICE Issued To: Richardson, Wesley G Orlando P. Hernandez, State Fire Marshal License Number SEO-2959652 Effective Date:02-07-2023 Expiration Date: 02-07-2024 This will serve as your proof of licensure with the State Fire Marshal's Office. To receive news and updates from the SFMO concerning fire industry licensing, sign up for the SFMO Licensing eNews updates oo-Qur we aite, FIREWORKS FLAME EFFECTS OPERATOR'S LICENSE TEXAS DEPARTMENT OF INSURANCE STATE FIRE MARSHAL'S OFFICE Issued To: Richardson, Wesley Orlando P. Hernandez, State Fire Marshal License Number FEO-2959651 Effective Date:02-07-2023 Expiration Date: 02-07-2024 This will serve as your proof of licensure with the State Fire Marshal's Office. To receive news and updates from the SFMO concerning fire industry licensing, sign up for the SFMO Licensing eNews updates on our website. Material Safety Data Sheet U.S. Department of Labor May be used to comply with OSHA's Hazard Communication Standard. Occupational Safety and Health 29 CFR 1910.1200. Standard must be consulted for specific requirements. Administration (Non -Mandatory Form) IDENTITY (As Used on Label and List) Note: Blank spaces are not permitted. If any item is not applicable or not RESPMA Premade Airburst, ALL SIZES, ALL COLORS information is available, the space must be marked to indicate that. SECTION I Manufacturer's Name Emergency Telephone Number RES Specialty Pyrotechnics, Inc. 800-255-3924 Address (Number, Street, City, State and ZIP Code) Telephone Number for Information 952-873-3113 21595 286`h Street Date Prepared Belle Plaine, MN 56011 November 29, 2000 Signature of Preparer (optional) SECTION II - Hazardous Ingredients/Identity Information Other Limits riazaraous components (specitic unemicai iaenmy: common ivame(s)): U jHA rtL AUU11i I LV Kecommenaeo %(uptional) POTASSIUM PERCHLORATE CAS#7778-74-7 10mg/m3 oral rat LD50: 2100 mg/kg POTASSIUM NITRATE Salt Peter N/A N/A oral rat LD50:3750 mg/kg BARIUM NITRATE 0.5 mg/m3 0.5mg/m3 STRONTIUM NITRATE CAS#10042-76-9 10mg/m3 oral rat LD50: 2750 mg/kg SODIUM BICARBONATE Baking Soda N/A N/A oral rat LD50: 4-8 g/kg COPPER OXIDE N/A 1mg/m3 ALUMINUM 15mg/m3 15mg/m3 ALUMINUM/MAGNESIUM ALLOY N/A N/A oral dog LD50: 230mg/kgSodium SODIUM OXALATE 10mg/kg SULFUR CAS#7704-34-9 none 10mg/m3 CHARCOAL N/A N/A Nuisance Dust ACCAROIDES RESIN Red Gum N/A 5mg/m3 (respirable fraction) DEXTRIN Starch 15mg/m3 10mg/m3 (Total Dust) BORIC ACID CAS#10043-35-3 N/A N/A oral rat LD50: 2660 mg/kg MAGNESIUM CARBONATE N/A N/A MAGNESIUM CAS#7439-95-4 N/A N/A BISMUTH OXIDE N/A N/A SODIUM BENZOATE N/A N/A VINYLIDENE CHLORIDE CAS#009011-06-7 N/A N/A NITROCELLULOSE 10mg/m3 SODIUM BENZOATE N/A N/A Contains a pyrotechnic composition, a solid mixture of fuel and oxidizer, which burns rapidly if ignited. These items are classified as II AG Explosives by the U.S. Department of Transportation. No chemical composition is exposed during normal storage and handling. SECTION III - Physical/Chemical Characteristics Boiling Point N/A Specific Gravity (H2O = 1) N/A Vapor Pressure (mm Hg.) N/A Melting Point Ignites Vapor Density (AIR = 1) N/A Evaporation Rate (Butyl Acetate = 1) N/A Solubility in Water Oxidizer component may dissolve after extended exposure to water Appearance and Odor Small pellets and granules contained in clear plastic wrapper, no odor SECTION IV - Fire and Explosion Hazard Data Flash Point (Method Used) Flammable Limits N/A LEL N/A UEL N/A N/A Extinguishing Media Water Special Fire Fighting Procedures Do not use suffocation methods, pyrotechnic composition supplies its own oxygen. Clear area and allow to burn out, then treat as normal fire. Unusual Fire and Explosion Hazards Devices may burn explosively and rupture storage containers. MSDS Page 1 of 2 SECTION V - Reactivitv Data Stability Unstable Conditions to Avoid: Heat, Sparks, Open flames, Static Electricity Stable X Incompatibility (Materials to Avoid) Acids, Water Hazardous Decomposition or Byproducts Oxides of Strontium, Barium, Metal alloys, Nitrogen and Hydrogen Chloride. Hazardous Polymerization May Occur Conditions to Avoid NONE Will Not Occur X SECTION VI - Health Hazard Data Routes of Entry Inhalation? NO Skin? NO Ingestion? NO Health Hazards (Acute and Chronic) Exposure to finished items does not pose any health hazard Carcinogenicity NTP? NO IARC Monographs? NO OSHA Regulated? NO Signs and Symptoms of Exposure Eye, skin and respiratory irritation possible. Medical Conditions Generally Aggravated By Exposure Pre-existing respiratory conditions such as asthma, allergies or sensitivity to ingredients. Emergency and First Aid Procedures Eyes: Flush with water. Respiratory: Remove patient to fresh air and contact physician if condition persists. SECTION VII - Precautions for Safe Handlina and Use Steps to be Taken in Case Material is Released or Spilled No smoking or open flames. Sweep spilled materials into cardboard container. Waste Disposal Method Dispose in compliance with state, federal and local regulations. Precautions to be Taken in Handling and Storing Keep materials cool and dry. Keep away from heat and other sources of possible ignition. Other Precautions NONE SECTION VIII - Control Measures Respiratory Protection (Specify Type) NONE Ventilation Local Exhaust Acceptable Special NONE Mechanical (General) Other Protective gloves None required Eye Protection Safety glasses recommended Other Protective Clothing or Equipment Cotton clothing Work/Hygienic Practice No smoking, eating or drinking when handling MSDS Page 2 of 2 Safety Data Sheet Section 1: Identification Product Name: Mines, Comets, & Falling Stars (All sizes with and without Tail) �T* ultratec special effects inc- Recommended use: Mines project a plume of bright points of color with or without sparkles Comets produce a large bright colored star with minimum smoke and virtually no fallout Professional Use only by a qualified Pyrotechnician in a Theatrical Entertainment Application or in Professional Training Applications. Manufacturer Ultratec Special Effects, Inc. and Distributor's 148 Moon drive Name and Address: Owens Cross Roads, AL 35763 United States Telephone Number: (256) 725-4224 www.ultratecfx.com Emergency Telephone Number: 800-255-3924 - ChemTel Section 2: Hazard Identification Chemicals have been withheld for trade secret and proprietary information purposes. 000 Burn, eye, skin, respiratory irritation, ingestion, acute or chronic exposure BURN: Wash affected area. EYE: Flush eyes with water for several minutes. SKIN: Wash with soap and water RESPIRATORY: Move to fresh air and consult physician. INGESTION: DO NOT INDUCE VOMITING, Contact poison control ACUTE OR CHRONIC EXPOSURE: Seek medical attention immediately SEEK MEDICAL ATTENTION IF YOU FEEL UNWELL Keep away from heat, sparks and open flame, hot surfaces - NO SMOKING Store in a cool dry approved area Dispose of content/container in accordance with local/regional/national and international regulations Section 3: Composition/Information on Ingredients Chemicals have been withheld for trade secret and proprietary information purposes. Section 4: First -Aid Measures BURN: Wash affected area. Skin: Wash with soap and water. Get medical attention if irritation develops EYE: Flush eyes with water for several minutes. RESPIRATORY: Move to fresh air and consult physician. INGESTION: DO NOT INDUCE VOMITING, Contact poison control ACUTE OR CHRONIC EXPOSURE: Seek medical attention immediately SEEK MEDICAL ATTENTION IF YOU FEEL UNWELL Section 5: Fire -Fighting Measures Extinguishing Media: Flood with water if a small number of pieces are involved. Special Fire Fighting Procedures: Do not use suffocation method; device contains its own oxygen. If large quantities are involved, allow them to burn and prevent spread of fire. Unusual Fire and Explosion Hazards: Items will burn rapidly in the event of ignition, and items may become airborne if not secured or contained. Section 6: Accidental Release Measures Personal precautions: Use personal protective equipment. Avoid breathing vapors, mist, or gas. Ensure adequate ventilation Methods and materials for containment and cleanup: Clean spills in a manner that does not disperse dust into the air Section 7: Handling and Storage Do not alter device. Do not remove from protective package until ready to use. Do not handle until all safety precautions have been read and understood. Use personal protection recommended in Section 8. Do not eat, drink or smoke when using this product. Use only in well -ventilated areas. Keep away from heat/sparks/open flames/hot surfaces. No smoking. All storage magazines must be safely located, or approved design and securely locked. Do not store improperly with other explosives (severe physical injury or death may occur from ignition). Store in accordance with all state, local, and federal regulations. Keep shipping and storage containers in cool, dry place. Do not crush, abrade, or subject these items to shock. Avoid open flames, smoking, and temperatures above 120F Section 8: Exposure Controls/ Personal Protection Respiratory Protection: None Ventilation: N/A Mechanical: N/A Local Exhaust: N/A Special: N/A Other: N/A Protective Gloves: N/A Eye Protection: Safety Glasses should be worn at all times for Pyrotechnic Operation Other Protective Clothing and Equipment: Wearing at least 60% cotton clothing is recommended. Work/Hygienic Practices: No smoking in the vicinity of item. Keep away from food. Wash hands thoroughly before eating or smoking. Exposure Limits: N/A Section 9: Physical and Chemical Properties Appearance: All pyrotechnic composition is contained within article Upper/Lower flammability or explosive limits: N/A Odor: no odor Vapor Pressure: N/A Odor Threshold: N/A Vapor Density: N/A pH: N/A Relative Density: N/A Melting Point/Freezing Point: N/A Solubility(ies): Slight Initial Boiling Point: N/A Flash Point: N/A Evaporation Rate: N/A Flammability: N/A Upper/Lower flammability or explosive limits: N/A Vapor Pressure: N/A Vapor Density: N/A Partition coefficient: n-octanol/water: N/A Auto -ignition Temperature: N/A Viscosity: N/A Section 10: Stability and Reactivity Stability: Stable Conditions to Avoid: Storage at temperatures above 120°F. Avoid friction, shock, open flames, smoking, or ignition sources including sparks, and static discharges. Items may deteriorate over time, dispose of items that exceed the Use By Date Incompatibility (Materials to Avoid): Exposure to water may cause item to deteriorate Hazardous Decomposition or Byproducts: Smoke, oxides, chlorides, and other gaseous and solid particulates Hazardous Polymerization: Will not occur Section 11: Toxicological Information Routes of Entry: Inhalation. Ingestion, skin contact, inhalation, eye contact Toxicity to Animals: Not available Chronic Effects on Humans: Exposure to finished items does not pose a health hazard. During function, the gases and smoke created may cause respiratory irritation if inhaled in large amounts. Device may cause thermal burns if used improperly. Other Toxic Effects on Humans: N/A Special Remarks on Toxicity to Animals: Not available Special Remarks on Chronic Effects on Humans: Not available Special Remarks on other Toxic Effects on Humans: Not available Acute Potential Health Effects: N/A Section 12: Ecological Information Ecotoxicity: Not available. BODS and COD: Not available. Products of Biodegradation: Not Available Toxicity of the Products of Biodegradation: Not available. Special Remarks on the Products of Biodegradation: Not available Section 13: Disposal Considerations Waste disposal: Waste must be disposed of in accordance with federal, state and local environmental control regulations. Steps to be taken in case material is released or spilled: No smoking or open flames in vicinity of broken or spilled items. Carefully pick up and place spilled items in container. Sweep up any exposed chemical composition with a natural fiber brush. Section 14: Transport Information DOT Classification: UN0431, IIAG Identification: Articles, Pyrotechnic for technical purposes Special Provisions for Transport: Not available Section 15: Other Regulatory Information Other regulatory information: N/A Section 16: Other Information References: Not available Other Special Considerations: Not available Created: 03/30/2015 The information above is believed to be accurate and represents the best information currently available to us. All Pyrotechnics should be used and handled with extreme caution, in accordance with all relevant regulations and codes only by experienced professional Pyrotechnicians. Safety Data Sheet go, rV / according to Regulation (EC) No 1907/2006 Universaldruckgasdose 330g 1600 ml Print date: 22.02.2016 Page 1 of 8 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Universaldruckgasdose 330g / 600 ml CFH-No. 47107, 48810, 52107, 70107, 70659, 70660, 70801 1.2. Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture Praparat Uses advised against No information available. 1.3. Details of the supplier of the safety data sheet Company name: CFH Lot- and Gasgerate GmbH Street: Bahnhofstr. 50 Place: D-74254 Offenau Telephone: +49 (0)7136 9594-0 e-mail: info@cfh-gmbh.de Contact person: Torsten Bogesch e-mail: bogesch.torsten@cfh-gmbh.de Responsible Department: info@cfh-gmbh.de 1.4. Emergency telephone +49(0) 551 - 1 92 40 (GIZ-Nord, 24h) number: SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Regulation (EC) No. 1272/2008 Hazard categories: Flammable gas: Flam. Gas 1 Hazard Statements: Extremely flammable gas. Contains gas under pressure; may explode if heated. 2.2. Label elements Regulation (EC) No. 1272/2008 Signal word Pictograms: Danger Telefax:+49 (0)7136 9594-44 Telephone:+49 (0)7136 9594-0 Hazard statements H220 Extremely flammable gas. H280 Contains gas under pressure; may explode if heated. Precautionary statements P101 If medical advice is needed, have product container or label at hand. P102 Keep out of reach of children. P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P260 Do not breathe dust/fume/gas/mist/vapours/spray. P251 Do not pierce or burn, even after use. Revision No: 1,01 GB - EN Revision date: 08.02.2016 Print date: 22.02.2016 P377 P381 P403 P410+P412 P501 Safety Data Sheet according to Regulation (EC) No 1907/2006 Universaldruckgasdose 330g / 600 ml Leaking gas fire: Do not extinguish, unless leak can be stopped safely. Eliminate all ignition sources if safe to do so. Store in a well -ventilated place. Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 'F. Dispose of waste according to applicable legislation. 2.3. Other hazards In use, may form flammable/explosive vapour -air mixture. Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50°C. Do not pierce or burn, even after use. Do not spray on a naked flame or any incandescent material. Keep away from sources of ignition - No smoking. Keep out of the reach of children. SECTION 3: Composition/information on ingredients 3.2. Mixtures Hazardous components CAS No Chemical name Quantity EC No Index No REACH No Classification according to Regulation (EC) No. 1272/2008 [CLP] 106-97-8 butane 50-75 % 203-448-7 01-2119474691-32 Flam. Gas 1, Compressed gas; H220 H280 74-98-6 propane 25-50 % 200-827-9 01-2119486944-21 Flam. Gas 1, Compressed gas; H220 H280 64742-49-0 Naphtha (petroleum), hydrotreated light <1 % 265-151-9 1 01-2119475133-43 Flam. Liq. 2, Skin Irrit. 2, STOT SE 3, Asp. Tox. 1, Aquatic Chronic 2; H225 H315 H336 H304 H411 Full text of H and EUH statements: see section 16. SECTION 4: First aid measures 4.1. Description of first aid measures General information Take off immediately all contaminated clothing. After inhalation Remove affected person from the danger area and lay down. Remove person to fresh air and keep comfortable for breathing. Call a doctor if you feel unwell. After contact with skin After contact with skin, wash immediately with plenty of water and soap. Take off immediately all contaminated clothing and wash it before reuse. After contact with eyes After contact with the eyes, rinse with water with the eyelids open for a sufficient length of time, then consult an ophthalmologist immediately. After ingestion not applicable 4.2. Most important symptoms and effects, both acute and delayed No information available. Revision No: 1,01 GB - EN Revision date: 08.02.2016 Safety Data Sheet according to Regulation (EC) No 1907/2006 Universaldruckgasdose 330g 1600 ml Print date: 22.02.2016 4.3. Indication of any immediate medical attention and special treatment needed No information available. SECTION 5: Firefighting measures 5.1. Extinquishinq media Suitable extinguishing media Dry extinguishing powder. Carbon dioxide (CO2). alcohol resistant foam. Unsuitable extinguishing media Full water jet 5.2. Special hazards arising from the substance or mixture Vapours are heavier than air, spread along floors and form explosive mixtures with air. 5.3. Advice for firefighters Protective equipment: No special measures are necessary. SECTION 6: Accidental release measures 6.1. Personal precautions. protective eauipment and emeraencv procedures Use personal protection equipment. 6.2. Environmental precautions In case of entry into waterways, soil or drains, inform the responsible authorities. 6.3. Methods and material for containment and cleaning up Provide adequate ventilation. 6.4. Reference to other sections Safe handling: see section 7 Personal protection equipment: see section 8 Disposal: see section 13 C SECTION 7: Handling and storage 7.1. Precautions for safe handling Advice on safe handling In use, may form flammable/explosive vapour -air mixture. Use only antistatically equipped (spark -free) tools. Wear anti -static footwear and clothing Advice on protection against fire and explosion r/• %0161 Page 3 of 8 Take precautionary measures against static discharges. Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50°C. Do not pierce or burn, even after use. Do not spray on naked flames or any incandescent material. 7.2. Conditions for safe storage, including any incompatibilities Requirements for storage rooms and vessels Keep container tightly closed in a cool, well -ventilated place. Protect from sunlight. Do no expose to temperatures exceeding 50°C/122°F. Do not keep the container sealed. Advice on storage compatibility Keep away from: Oxidising agent 7.3. Specific end use(s) No information available. Revision No: 1,01 GB - EN Revision date: 08.02.2016 Safety Data Sheet according to Regulation (EC) No 1907/2006 Universaldruckgasdose 330g / 600 ml Print date: 22.02.2016 LSECTION 8: Exposure controls/personal protection 8.1. Control parameters Exposure limits (EH40) f1l, Z0,00?1z go 1 %Pil Page 4 of 8 CAS No Substance ppm mg/m' fibres/ml Category Origin 106-97-8 Butane 600 750 1450 1810 TWA (8 h) STEL (15 min) WEL WEL 8.2. Exposure controls Appropriate engineering controls Provide adequate ventilation as well as local exhaustion at critical locations. Protective and hygiene measures Avoid contact with skin, eyes and clothes. Wash hands before breaks and after work. Eye/face protection goggles Hand protection Tested protective gloves must be worn Skin protection Only wear fitting, comfortable and clean protective clothing. Respiratory protection In case of inadequate ventilation wear respiratory protection. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state: liquefied gas Colour: colourless Odour: characteristic Test method pH -Value: Changes in the physical state Melting point: Initial boiling point and boiling range: Sublimation point: Softening point: Pour point: not applicable not determined not determined not determined not determined not determined not determined Flash point: not determined Sustaining combustion: Not sustaining combustion Flammability Solid: not determined Gas: not determined Explosive properties Vapours are heavier than air, spread along floors and form explosive mixtures with air. Lower explosion limits: 1,5 vol. % Revision No: 1,01 GB - EN Revision date: 08.02.2016 Safety Data Sheet rV / according to Regulation (EC) No 1907/2006 Universaldruckgasdose 330g 1600 ml Print date: 22.02.2016 Page 5 of 8 Upper explosion limits: 10,9 Vol. % Ignition temperature: 365 °C Auto -ignition temperature Solid: not determined Gas: not determined Decomposition temperature: not determined Oxidizing properties not determined Vapour pressure: 8300 hPa (at 20 °C) Density (at 20 °C): 0,6 g/cm' Water solubility: not determined Solubility in other solvents not determined Partition coefficient: not determined Viscosity / dynamic: not determined Viscosity / kinematic: not determined Vapour density: not determined Evaporation rate: not determined 9.2. Other information No information available. SECTION 10: Stability and reactivity 10.1. Reactivity In use, may form flammable/explosive vapour -air mixture. 10.2. Chemical stability The substance is chemically stable under recommended conditions of storage, use and temperature. 10.3. Possibility of hazardous reactions No information available. 10.4. Conditions to avoid Pressurised container: May burst if heated. 10.5. Incompatible materials No information available. 10.6. Hazardous decomposition products No information available. SECTION 11: Toxicological information 11.1. Information on toxicoloaical effects Acute toxicity CAS No Chemical name Exposure routes Method Dose Species Source 106-97-8 butane inhalative (4 h) gas LC50 273000 ppm Rat GESTIS Revision No: 1,01 GB - EN Revision date: 08.02.2016 Safety Data Sheet according to Regulation (EC) No 1907/2006 Universaldruckgasdose 330g 1600 ml Print date: 22.02.2016 SECTION 12: Ecological information 12.1. Toxicity No information available. r/• %0161 Page 6 of 8 CAS No Chemical name Aquatic toxicity Method Dose I [h] I [d] Species Source 106-97-8 butane Acute fish toxicity LC50 27,98 mg/I 1 96 h Fish, no other information ECHA Acute algae toxicity ErC50 7,71 mg/I 1 96 h Green al ea JECHA 74-98-6 propane Acute fish toxicity LC50 27,98 mg/I 1 96 h Fish, no other information ECHA Acute algae toxicity ErC50 7,71 mg/I 96 h Green algea ECHA 12.2. Persistence and degradability No information available. 12.3. Bioaccumulative potential Partition coefficient n-octanol/water CAS No Chemical name Log Pow 106-97-8 butane 2,89 74-98-6 propane 2,36 12.4. Mobility in soil No information available. 12.5. Results of PBT and vPvB assessment The substances in the mixture do not meet the PBT/vPvB criteria according to REACH, annex XIII. 12.6. Other adverse effects No information available. SECTION 13: Disposal considerations 13.1. Waste treatment methods Advice on disposal Dispose of waste according to applicable legislation. Contaminated packaging Dispose of waste according to applicable legislation. SECTION 14: Transport information Land transport (ADR/RID) 14.1. UN number: 14.2. UN Droner shiDDina name: 14.3. Transoort hazard class(es): 14.4. Packina arouD: Hazard label: Classification code: Special Provisions: Limited quantity: Excepted quantity: Transport category: Tunnel restriction code UN 2037 Receptacles, small, containing gas (gas cartridges) 2 2.1 5F 191 303 344 1L EO 2 D Revision No: 1,01 GB - EN Revision date: 08.02.2016 Print date: 22.02.2016 Inland waterways transport (ADN) 14.1. UN number: 14.2. UN proper shipping name: 14.3. Transport hazard class(es): 14.4. Packing group: Hazard label: Classification code: Special Provisions: Limited quantity: Excepted quantity: Marine transport (IMDG) 14.1. UN number: 14.2. UN proper shipping name: 14.3. Transport hazard class(es): 14.4. Packing group: Hazard label: Special Provisions: Limited quantity: Excepted quantity: EmS: Air transport (ICAO) 14.1. UN number: 14.2. UN proper shipping name: 14.3. Transport hazard class(es): 14.4. Packing group: Hazard label: Special Provisions: Limited quantity Passenger: Passenger LQ: Excepted quantity: IATA-packing instructions - Passenger: IATA-max. quantity - Passenger: IATA-packing instructions - Cargo: IATA-max. quantity - Cargo: 14.5. Environmental hazards ENVIRONMENTALLY HAZARDOUS: 14.6. Special precautions for user No information available. Safety Data Sheet according to Regulation (EC) No 1907/2006 Universaldruckgasdose 330g / 600 ml UN 2037 Receptacles, small, containing gas (gas cartridges) 2 2.1 5F 191 303 344 1L EO UN 2037 Receptacles, small, containing gas (gas cartridges) 2.1 2.1 191, 277, 303, 344 1000 mL EO F-D,S-U UN 2037 Receptacles, small, containing gas (gas cartridges) 2.1 2.1 A167 A802 1 kg Y203 EO no 203 1 kg 203 15 kg 14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code No information available. SECTION 15: Regulatory information f1l, Z0,00?1z go 1 %toil 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture EU regulatory information Information according to 2012/18/EU P2 FLAMMABLE GASES (SEVESO III): Additional information: Page 7 of 8 Revision No: 1,01 GB - EN Revision date: 08.02.2016 Print date: 22.02.2016 National regulatory information Water contaminating class (D): 15.2. Chemical safety assessment Safety Data Sheet according to Regulation (EC) No 1907/2006 Universaldruckgasdose 330g / 600 ml - - not water contaminating For the following substances of this mixture a chemical safety assessment has been carried out: butane propane Naphtha (petroleum), hydrotreated light SECTION 16: Other information Abbreviations and acronyms ADR: Accord europeen sur le transport des marchandises dangereuses par Route (Regelung zum Transport gefahrlicher Guter auf der Stral1e) (European Agreement concerning the International Carriage of Dangerous Goods by Road) CAS: Chemical Abstracts Service CLP: Classification, Labelling & Packaging (Einstufung, Kennzeichnung and Verpackung) DIN: Deutsches Institut fur Normung EG: Europaische Gemeinschaft Eye Irr.: Serious eye irritation (schwere Augenreizung) IATA: International Air Transport Association (Internationale Luftverkehrsvereinigung) IMDG: International Maritime Code for Dangerous Goods (Regelung zum Transport gef(Ahrlicher Guter mit Seeschiffen ) ISO: Internationale Organisation fur Normung PBT: Persistent, Bioaccumulative and Toxic (Persistent, Bioakkumulierbar and toxisch) RID: Reglement concernant le transport international ferroviaire des marchandises dangereuses (Regelung zum Transport gefahrlicher Guter im Schienenverkehr) Skin Irr.: Skin irritation (Hautreizung) VOC: Volatile Organic Compound (fluchtige organische Verbindung) vPvB: Very Persistent and very Bioaccumulative (sehr persistent and sehr Bioakkumulierbar) Relevant H and EUH statements (number and full text) H220 Extremely flammable gas. H225 Highly flammable liquid and vapour. H280 Contains gas under pressure; may explode if heated. H304 May be fatal if swallowed and enters airways. H315 Causes skin irritation. H336 May cause drowsiness or dizziness. H411 Toxic to aquatic life with long lasting effects. f1l, Z0,00?1z go 1 %toil Further Information The above information describes exclusively the safety requirements of the product and is based on our present-day knowledge. The information is intended to give you advice about the safe handling of the product named in this safety data sheet, for storage, processing, transport and disposal. The information cannot be transferred to other products. In the case of mixing the product with other products or in the case of processing, the information on this safety data sheet is not necessarily valid for the new made-up material. Page 8 of 8 (The data for the hazardous ingredients were taken respectively from the last version of the sub -contractor's safety data sheet.) Revision No: 1,01 GB - EN Revision date: 08.02.2016 SAFETY DATA SHEET Airgas. Propane an Air Liquide company Section 1. Identification GHS product identifier Propane Chemical name propane Other means of Propyl hydride; n-Propane; Dimethyl methane; Bottled gas; propane in gaseous state; identification propane liquefied, n-Propane; Dimethylmethane; Freon 290; Liquefied petroleum gas; Lpg; Propyl hydride; R 290; C3H8; UN 1075; UN 1978; A-108; Hydrocarbon propellant. Product type Liquefied gas Product use Synthetic/Analytical chemistry. Synonym Propyl hydride; n-Propane; Dimethyl methane; Bottled gas; propane in gaseous state; propane liquefied, n-Propane; Dimethylmethane; Freon 290; Liquefied petroleum gas; Lpg; Propyl hydride; R 290; C3H8; UN 1075; UN 1978; A-108; Hydrocarbon propellant. SDS # 001045 Supplier's details Airgas USA, LLC and its affiliates 259 North Radnor -Chester Road Suite 100 Radnor, PA 19087-5283 1-610-687-5253 24-hour telephone : 1-866-734-3438 Section 2. Hazards identification OSHA/HCS status This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). Classification of the FLAMMABLE GASES - Category 1 substance or mixture GASES UNDER PRESSURE - Liquefied gas GHS label elements Hazard pictograms Signal word Danger Hazard statements Extremely flammable gas. Contains gas under pressure; may explode if heated. May cause frostbite. May displace oxygen and cause rapid suffocation. May form explosive mixtures with air. Precautionary statements General Read and follow all Safety Data Sheets (SDS'S) before use. Read label before use. Keep out of reach of children. If medical advice is needed, have product container or label at hand. Close valve after each use and when empty. Use equipment rated for cylinder pressure. Do not open valve until connected to equipment prepared for use. Use a back flow preventative device in the piping. Use only equipment of compatible materials of construction. Always keep container in upright position. Approach suspected leak area with caution. Prevention Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Response Leaking gas fire: Do not extinguish, unless leak can be stopped safely. In case of leakage, eliminate all ignition sources. Storage Protect from sunlight. Store in a well -ventilated place. Date of issue/Date of revision : 1111512020 Date of previous issue : 101512020 Version : 1.02 1112 Propane Section 2. Hazards identification Disposal Not applicable. Hazards not otherwise Liquid can cause burns similar to frostbite. classified Section 3. Composition/information on ingredients Substance/mixture Substance Chemical name propane Other means of Propyl hydride; n-Propane; Dimethyl methane; Bottled gas; propane in gaseous state; identification propane liquefied, n-Propane; Dimethylmethane; Freon 290; Liquefied petroleum gas; Lpg; Propyl hydride; R 290; C3H8; UN 1075; UN 1978; A-108; Hydrocarbon propellant. Product code 001045 CAS number/other identifiers CAS number 74-98-6 Ingredient name % CAS number Propane 100 74-98-6 Any concentration shown as a range is to protect confidentiality or is due to batch variation. There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Occupational exposure limits, if available, are listed in Section 8. Section 4. First aid measures Description of necessary first aid measures Eye contact Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention if irritation occurs. Inhalation Remove victim to fresh air and keep at rest in a position comfortable for breathing. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention if adverse health effects persist or are severe. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Skin contact Wash contaminated skin with soap and water. Remove contaminated clothing and shoes. To avoid the risk of static discharges and gas ignition, soak contaminated clothing thoroughly with water before removing it. Get medical attention if symptoms occur. In case of contact with liquid, warm frozen tissues slowly with lukewarm water and get medical attention. Do not rub affected area. Wash clothing before reuse. Clean shoes thoroughly before reuse. Ingestion Remove victim to fresh air and keep at rest in a position comfortable for breathing. Get medical attention if adverse health effects persist or are severe. Ingestion of liquid can cause burns similar to frostbite. If frostbite occurs, get medical attention. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. As this product rapidly becomes a gas when released, refer to the inhalation section. Most important symptoms/effects, acute and delayed Potential acute health effects Eye contact Liquid can cause burns similar to frostbite. Inhalation No known significant effects or critical hazards. Skin contact Dermal contact with rapidly evaporating liquid could result in freezing of the tissues or frostbite. Date of issue/Date of revision : 1111512020 Date of previous issue : 101512020 Version : 1.02 2112 Propane Section 4. First aid measures Frostbite Try to warm up the frozen tissues and seek medical attention. Ingestion Ingestion of liquid can cause burns similar to frostbite. Over -exposure sians/svmotoms Eye contact Adverse symptoms may include the following:, frostbite Inhalation No specific data. Skin contact Adverse symptoms may include the following:, frostbite Ingestion Adverse symptoms may include the following:, frostbite Indication of immediate medical attention and special treatment needed. if necessa Notes to physician Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. Specific treatments No specific treatment. Protection of first-aiders No action shall be taken involving any personal risk or without suitable training. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. See toxicological information (Section 11) Section 5. Fire -fighting measures Extinguishing media Suitable extinguishing Use an extinguishing agent suitable for the surrounding fire. media Unsuitable extinguishing None known. media Specific hazards arising Contains gas under pressure. Extremely flammable gas. In a fire or if heated, a from the chemical pressure increase will occur and the container may burst, with the risk of a subsequent explosion. The vapor/gas is heavier than air and will spread along the ground. Gas may accumulate in low or confined areas or travel a considerable distance to a source of ignition and flash back, causing fire or explosion. Hazardous thermal Decomposition products may include the following materials: decomposition products carbon dioxide carbon monoxide Special protective actions Promptly isolate the scene by removing all persons from the vicinity of the incident if for fire-fighters there is a fire. No action shall be taken involving any personal risk or without suitable training. Contact supplier immediately for specialist advice. Move containers from fire area if this can be done without risk. Use water spray to keep fire -exposed containers cool. If involved in fire, shut off flow immediately if it can be done without risk. If this is impossible, withdraw from area and allow fire to burn. Fight fire from protected location or maximum possible distance. Eliminate all ignition sources if safe to do so. Special protective Fire-fighters should wear appropriate protective equipment and self-contained breathing equipment for fire-fighters apparatus (SCBA) with a full face -piece operated in positive pressure mode. For incidents involving large quantities, thermally insulated undergarments and thick textile or leather gloves should be worn. Section 6. Accidental release measures Personal precautions, protective equipment and emergency procedures For non -emergency Accidental releases pose a serious fire or explosion hazard. No action shall be taken personnel involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Avoid breathing gas. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment. Date of issue/Date of revision : 1111512020 Date of previous issue : 101512020 Version : 1.02 3112 Propane Section 6. Accidental release measures For emergency responders : If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non - emergency personnel". Environmental precautions Ensure emergency procedures to deal with accidental gas releases are in place to avoid contamination of the environment. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Methods and materials for containment and cleanina u Small spill Immediately contact emergency personnel. Stop leak if without risk. Use spark -proof tools and explosion -proof equipment. Large spill Immediately contact emergency personnel. Stop leak if without risk. Use spark -proof tools and explosion -proof equipment. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. Section 7. Handling and storage Precautions for safe handling Protective measures Put on appropriate personal protective equipment (see Section 8). Contains gas under pressure. Do not get in eyes or on skin or clothing. Avoid breathing gas. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Do not puncture or incinerate container. Use equipment rated for cylinder pressure. Close valve after each use and when empty. Protect cylinders from physical damage; do not drag, roll, slide, or drop. Use a suitable hand truck for cylinder movement. Use only non -sparking tools. Empty containers retain product residue and can be hazardous. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion -proof electrical (ventilating, lighting and material handling) equipment. Advice on general Eating, drinking and smoking should be prohibited in areas where this material is occupational hygiene handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures. Conditions for safe storage, : Store in accordance with local regulations. Store in a segregated and approved area. including any Store away from direct sunlight in a dry, cool and well -ventilated area, away from incompatibilities incompatible materials (see Section 10). Eliminate all ignition sources. Cylinders should be stored upright, with valve protection cap in place, and firmly secured to prevent falling or being knocked over. Cylinder temperatures should not exceed 52 °C (125 °F). Keep container tightly closed and sealed until ready for use. See Section 10 for incompatible materials before handling or use. Section 8. Exposure controls/personal protection Control parameters Occupational exposure limits Ingredient name Exposure limits Propane NIOSH REL (United States, 10/2016). TWA: 1800 mg/m3 10 hours. TWA: 1000 ppm 10 hours. OSHA PEL (United States, 5/2018). TWA: 1800 mg/m3 8 hours. TWA: 1000 ppm 8 hours. OSHA PEL 1989 (United States, 3/1989). TWA: 1800 mg/m3 8 hours. TWA: 1000 ppm 8 hours. ACGIH TLV (United States, 3/2019). Oxygen Depletion [Asphyxiant]. Explosive potential. Date of issue/Date of revision : 1111512020 Date of previous issue : 101512020 Version : 1.02 4112 Propane Section 8. Exposure controls/personal protection Appropriate engineering Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or controls other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion -proof ventilation equipment. Environmental exposure Emissions from ventilation or work process equipment should be checked to ensure controls they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. Individual protection measures Hygiene measures Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Eye/face protection Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: safety glasses with side - shields. Skin protection Hand protection Chemical -resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. If contact with the liquid is possible, insulated gloves suitable for low temperatures should be worn. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated. Body protection Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. When there is a risk of ignition from static electricity, wear anti- static protective clothing. For the greatest protection from static discharges, clothing should include anti -static overalls, boots and gloves. Other skin protection Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Respiratory protection Based on the hazard and potential for exposure, select a respirator that meets the appropriate standard or certification. Respirators must be used according to a respiratory protection program to ensure proper fitting, training, and other important aspects of use. Thermal hazards If there is a risk of contact with the liquid, all protective equipment worn should be suitable for use with extremely low temperature materials. Section 9. Physical and chemical properties Appearance Physical state Gas. Color Colorless. Odor Odorless.BUT MAY HAVE SKUNK ODOR ADDED. Odor threshold Not available. pH Not available. Melting point -187.E°C (-305.7°F) Boiling point -42.1 °C (-43.8°F) Date of issue/Date of revision : 1111512020 Date of previous issue : 101512020 Version : 1.02 5112 Propane Section 9. Physical and chemical properties Critical temperature Flash point Evaporation rate Flammability (solid, gas) Lower and upper explosive (flammable) limits Vapor pressure Vapor density Specific Volume (ft s/Ib) Gas Density (lb/ft 3) Relative density Solubility Solubility in water Partition coefficient: n- octanol/water Auto -ignition temperature Decomposition temperature Viscosity Flow time (ISO 2431) Molecular weight Aerosol product Heat of combustion 96.55°C (205.8°F) Closed cup: -104°C (-155.2°F) Open cup: -104°C (-155.2°F) Not available. Extremely flammable in the presence of the following materials or conditions: open flames, sparks and static discharge and oxidizing materials. Lower:1.8% Upper: 8.4% 109 (psig) 1.6 (Air = 1) 8.6206 0.116 (25°C / 77 to °F) Not applicable. Not available. 0.0244 g/I 1.09 287°C (548.6°F) Not available. Not applicable. Not available. 44.11 g/mole -46012932 J/kg Section 10. Stability and reactivity Reactivity : No specific test data related to reactivity available for this product or its ingredients. Chemical stability : The product is stable. Possibility of hazardous Under normal conditions of storage and use, hazardous reactions will not occur. reactions Conditions to avoid Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld, braze, solder, drill, grind or expose containers to heat or sources of ignition. Do not allow gas to accumulate in low or confined areas. Incompatible materials : Oxidizers Hazardous decomposition Under normal conditions of storage and use, hazardous decomposition products should products not be produced. Hazardous polymerization : Under normal conditions of storage and use, hazardous polymerization will not occur. Date of issue/Date of revision : 1111512020 Date of previous issue : 101512020 Version : 1.02 6112 Propane Section 11. Toxicological information Information on toxicological effects Acute toxicity Not available. Irritation/Corrosion Not available. Sensitization Not available. Mutagenicity Not available. Carcinogenicity Not available. Reproductive toxicity Not available. Teratogenicity Not available. Specific target organ toxicity (single exposure) Not available. Specific target organ toxicity (repeated exposure) Not available. Aspiration hazard Not available. Information on the likely Not available. routes of exposure Potential acute health effects Eye contact Liquid can cause burns similar to frostbite. Inhalation No known significant effects or critical hazards. Skin contact Dermal contact with rapidly evaporating liquid could result in freezing of the tissues or frostbite. Ingestion Ingestion of liquid can cause burns similar to frostbite. Symptoms related to the physical, chemical and toxicological characteristics Eye contact Adverse symptoms may include the following:, frostbite Inhalation No specific data. Skin contact Adverse symptoms may include the following:, frostbite Ingestion Adverse symptoms may include the following:, frostbite Delayed and immediate effects and also chronic effects from short and long term exposure Short term exposure Potential immediate Not available. effects Potential delayed effects Not available. Long term exposure Potential immediate Not available. effects Potential delayed effects Not available. Date of issue/Date of revision : 1111512020 Date of previous issue : 101512020 Version : 1.02 7112 Propane Section 11. Toxicological information Potential chronic health effects Not available. General Carcinogenicity Mutagenicity Teratogenicity Developmental effects Fertility effects Numerical measures of toxicity Acute toxicity estimates Not available. No known significant effects or critical hazards. No known significant effects or critical hazards. No known significant effects or critical hazards. No known significant effects or critical hazards. No known significant effects or critical hazards. No known significant effects or critical hazards. Section 12. Ecological information Toxicitv Not available. Persistence and degradability Not available. Bioaccumulative potential Product/ingredient name LogP.. BCF Potential Propane 1.09 - low Mobility in soil Soil/water partition Not available. coefficient (Koc) Other adverse effects : No known significant effects or critical hazards. Section 13. Disposal considerations Disposal methods The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non -recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Empty Airgas-owned pressure vessels should be returned to Airgas. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Empty containers or liners may retain some product residues. Do not puncture or incinerate container. Date of issue/Date of revision : 1111512020 Date of previous issue : 101512020 Version : 1.02 8112 Propane Section 14. Transport information DOT TDG Mexico IMDG IATA UN number UN1978 UN1978 UN1978 UN1978 UN1978 UN proper PROPANE SEE PROPANE PROPANE SEE PROPANE PROPANE shipping name ALSO ALSO PETROLEUM PETROLEUM GASES, GASES, LIQUEFIED LIQUEFIED (propane) Transport 2.1 2.1 2.1 2.1 2.1 hazard class(es) Packing group - - - - - Environmental No. No. No. No. No. hazards "Refer to CFR 49 (or authority having jurisdiction) to determine the information required for shipment of the product." Additional information DOT Classification Limited quantity Yes. Packaging instruction Passenger aircraft Quantity limitation: Forbidden. Cargo aircraft Quantity limitation: 150 kg Special provisions 19, T50 For domestic transportation only, UN1075 may be substituted for the UN number shown as long as the substitution is consistent on package markings, shipping papers, and emergency response information. See 49 CFR 172.102 Special Provision 19. Containers of NON-ODORIZED liquefied petroleum gas must be marked either NON-ODORIZED or NOT ODORIZED as of September 30, 2006. [49 CFR 172.301(f), 326(d), 330(c) and 338(e)] TDG Classification Product classified as per the following sections of the Transportation of Dangerous Goods Regulations: 2.13-2.17 (Class 2). Explosive Limit and Limited Quantity Index 0.125 ERAP Index 3000 Passenger Carrying Vessel Index 65 Passenger Carrying Road or Rail Index Forbidden Special provisions 29, 42 IATA Quantity limitation Passenger and Cargo Aircraft: Forbidden. Cargo Aircraft Only: 150 kg. Special precautions for user : Transport within user's premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage. Date of issue/Date of revision : 1111512020 Date of previous issue : 101512020 Version : 1.02 9112 Propane Section 14. Transport information Transport in bulk according : Not available. to IMO instruments Section 15. Regulatory information U.S. Federal regulations TSCA 8(a) CDR Exempt/Partial exemption: Not determined Clean Air Act (CAA) 112 regulated flammable substances: propane Clean Air Act Section 112 Not listed (b) Hazardous Air Pollutants (HAPs) Clean Air Act Section 602 Not listed Class I Substances Clean Air Act Section 602 Not listed Class II Substances DEA List I Chemicals Not listed (Precursor Chemicals) DEA List II Chemicals Not listed (Essential Chemicals) SARA 302/304 Composition/information on inaredients No products were found. SARA 304 RQ Not applicable. SARA 311 /312 Classification Refer to Section 2: Hazards Identification of this SDS for classification of substance. State reaulations Massachusetts This material is listed. New York This material is not listed. New Jersey This material is listed. Pennsylvania This material is listed. California Prop. 65 This product does not require a Safe Harbor warning under California Prop. 65. International regulations Chemical Weapon Convention List Schedules I. II & III Chemicals Not listed. Montreal Protocol Not listed. Stockholm Convention on Persistent Oraanic Pollutants Not listed. Rotterdam Convention on Prior Informed Consent (PIC) Not listed. UNECE Aarhus Protocol on POPS and Heavy Metals Not listed. Inventory list Australia This material is listed or exempted. Canada This material is listed or exempted. China This material is listed or exempted. Europe This material is listed or exempted. Date of issue/Date of revision : 1111512020 Date of previous issue : 101512020 Version : 1.02 10112 Propane Section 15. Regulatory information Japan Japan inventory (ENCS): This material is listed or exempted. Japan inventory (ISHL): This material is listed or exempted. New Zealand This material is listed or exempted. Philippines This material is listed or exempted. Republic of Korea This material is listed or exempted. Taiwan This material is listed or exempted. Thailand Not determined. Turkey This material is listed or exempted. United States This material is active or exempted. Viet Nam This material is listed or exempted. Section 16. Other information Hazardous Material Information System (U.S.A.) / 2 Flammability 4 Physical hazards 0 Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks. Although HMIS® ratings and the associated label are not required on SDSs or products leaving a facility under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered trademark and service mark of the American Coatings Association, Inc. The customer is responsible for determining the PPE code for this material. For more information on HMIS® Personal Protective Equipment (PPE) codes, consult the HMIS® Implementation Manual. National Fire Protection Association (U.S.A.) Flammability Health 0 Instability/Reactivity Special Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency Response Copyright ©1997, National Fire Protection Association, Quincy, MA 02269. This reprinted material is not the complete and official position of the National Fire Protection Association, on the referenced subject which is represented only by the standard in its entirety. Copyright ©2001, National Fire Protection Association, Quincy, MA 02269. This warning system is intended to be interpreted and applied only by properly trained individuals to identify fire, health and reactivity hazards of chemicals. The user is referred to certain limited number of chemicals with recommended classifications in NFPA 49 and NFPA 325, which would be used as a guideline only. Whether the chemicals are classified by NFPA or not, anyone using the 704 systems to classify chemicals does so at their own risk. Procedure used to derive the classification Classification Justification FLAMMABLE GASES - Category 1 GASES UNDER PRESSURE - Liquefied gas Expert judgment Expert judgment History Date of printing 11/15/2020 Date of issue/Date of 11/15/2020 revision Date of previous issue 10/5/2020 Version 1.02 Date of issue/Date of revision : 1111512020 Date of previous issue : 101512020 Version : 1.02 11112 Propane Section 16. Other information Key to abbreviations ATE = Acute Toxicity Estimate BCF = Bioconcentration Factor GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association IBC = Intermediate Bulk Container IMDG = International Maritime Dangerous Goods LogPow = logarithm of the octanol/water partition coefficient MARPOL = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution) UN = United Nations References Not available. Other special The information below is given to call attention to the issue of "Naturally occurring considerations radioactive materials". Although Radon-222 levels in the product represented by this MSDS do not present any direct Radon exposure hazard, customers should be aware of the potential for Radon daughter build up within their processing systems, whatever the source of their product streams. Radon-222 is a naturally occurring radioactive gas which can be a contaminant in natural gas. During subsequent processing , Radon tends to be concentrated in Liquefied Petroleum Gas streams and in product streams having a similar boiling point range. Industry experience has shown that this product may contain small amounts of Radon-222 and its radioactive decay products, called Radon "daughters". The actual concentration of Radon-222 and radioactive daughters in the delivered product is dependent on the geographical source of the natural gas and storage time prior to delivery. Process equipment (i.e. lines, filters, pumps and reaction units) may accumulate significant levels of radioactive daughters and show a gamma radiation reading during operation. A potential external radiation hazard exists at or near any pipe valve or vessel containing a Radon enriched stream, or containing internal deposits of radioactive material due to the transmission of gamma radiation through its wall. Field studies reported in the literature have not shown any conditions that subject workers to cumulative exposures in excess of general population limits. Equipment emitting gamma radiation should be presumed to be internally contaminated with alpha emitting decay products which may be a hazard if inhaled or ingested. Protective equipment such as coveralls, gloves, and respirator (NIOSH/MHSA approved for high efficiency particulates and radionuclides, or supplied air) should be worn by personnel entering a vessel or working on contaminated process equipment to prevent skin contamination, ingestion, or inhalation of any residues containing alpha radiation. Airborne contamination may be minimized by handling scale and/or contaminated materials in a wet state. Notice to reader To the best of our knowledge, the information contained herein is accurate. However, neither the above -named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. Date of issue/Date of revision : 1111512020 Date of previous issue : 101512020 Version : 1.02 12112 Star S Productions SFX 1224 Corporate Dr. W. Ste F. Arlington, TX 76005 From: Jamie Smith: Star S Productions SFX Offices: 817-652-3555 Mobile: 214-549-1064 starsp@wt.net I9W_lMI1:1 I99:14111W_\0 Product Description: Item Name Altitude Duration Performance Quantity Stage Flames 15' -18' 1-3 second burst Column of Fire 6 201b Propane Tanks 4 Flame Effect Description: The Stage Flame is a propane flame unit that can be directly operated off the fuel tank with no accumulator. The Stage Flame is capable of 15-18ft flame height but can be adjusted for lower heights as well. The Stage Flames complies with NFPA 160 and is a direct ignition system with separate E-Stop Flame Effect Classification: Type 3 Manually Fired Location of Flame Effects: See Site Plan Control of Flame Effects: Operator supervision with flame effect in open view. Flame effects are direct ignition flame effects controlled via DMX controller with separate E-Stop. Control Sequence: Release E-Stop and actuate flame effect button Location of Flame Effects are shown on the Site Plan The Area effected by the Flame Effects are shown on the site plan The locations of the Audience shown on the site plan Fuels Used: Portable LPG 201b tanks Ventilation: Ventilation air is not directly used to exhaust the products of combustion Flammables materials piping Propane rated HP Hose Storage and Holding Area: NA Supplemental Fire Protection Features: 2- H2O & 2- BC Fire Extinguishers. Emergence Response Procedure for Flame Effects In case of an emergency the first thing is to inform the local FM Standby of the emergency situation. If spectators need to be evacuated, it will be the responsibility of the venue security. If there is a fire emergency on stage, the first action is to engage the E-Stop which will shut down the fuel valve and eliminate any discharge of propane and then shut down all pyro control systems. If there is a fire on stage, the flame effect operator will clear the stage for safety and evaluate the situation to determine if they should proceed to extinguish the fire with the fire extinguishers provided. After the fire is extinguished, the flame effect operator will inform the FM Standby of the status of the safety of the stage. At that point a fire investigation and report will be made to determine the cause of the fire emergency. Means of Egress Venue security will direct spectators to the nearest fire exit. The Stage Flame is primarily constructed of aluminum, brass, and steel. By nature, these materials are flame retardant SIDS Sheet on Propane attached. Flame Effect Operator: Wes Richardson/ shown on Cover Sheet Overview: • We will provide pyro augmentations for the Koe Wetzel Band • We will provide 6 Stage Flames that operate on 201b propane tanks • We will provide 24 Low Altitude Airburst Fire Extinguishers: 2 H2O, 2 BC See attached SFX Flame Effect Site Plan